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<p>名稱(chēng)：西安金沃泰環(huán)?？萍加邢薰?br>
地址：西安市雁塔區科技西路</p>
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<td height="43" align="center" valign="top"><span style="font-size:16px; color: #666666;"><b>二溴丙烷廢氣的治理與回收技術(shù)</b></span></td>
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<td height="40" style="border-bottom: 1px dashed #d9d9d9;"><font color="#999999">作者：西安金沃泰環(huán)?？萍加邢薰?/font> <font color="#999999">發(fā)稿日期：2021-03-03 11:36:33</font></td>
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<td align="left" class="neirong" style="padding-top: 30px;">二溴丙烷沸點(diǎn)高，在工業(yè)生產(chǎn)及應用時(shí)容易揮發(fā)造成環(huán)境污染。目前常用的治理二溴丙烷廢氣的工藝有低溫冷凝法，焚燒法和活性炭吸附法等。<br />
低溫冷凝法是利用二溴丙烷的飽和蒸汽壓隨著(zhù)溫度的降低而降低的關(guān)系，降低溫度至零度以下,使其由氣態(tài)二溴丙烷盡量液化的工藝。該工藝對于高濃度的二溴丙烷廢氣具有良好的回收效果，但冷凝不徹底，仍然會(huì )有較高濃度的廢氣排出，很難做到達標排放。<br />
焚燒法是常用的低濃度廢氣處理工藝，常見(jiàn)的為RTO（蓄熱式燃燒）,利用高溫將二溴丙烷分解,燃燒后一般會(huì )形成酸性氣體，對RTO設備的壽命影響非常大，同時(shí)容易形成二噁英類(lèi)污染因子。由于種種原因，該工藝實(shí)際應用非常少。<br />
活性炭吸附法是利用活性炭的吸附性，將廢氣中的二溴丙烷進(jìn)行吸附，再通過(guò)蒸汽吹脫回收二溴丙烷的工藝。該工藝中活性炭吸附效果受水分影響較大，經(jīng)過(guò)多次吹脫再生后吸附性能下降明顯；且二溴丙烷易被活性炭中的雜質(zhì)催化分解而產(chǎn)生酸性氣體，遇水變?yōu)樗岷髮υO備腐蝕嚴重，縮短管道設備使用壽命。<br />
針對目前二溴丙烷廢氣處理存在的問(wèn)題，江蘇海普功能材料有限公司研制出HDV型高分子納米吸附劑，可將廢氣中的二溴丙烷吸附去除。吸附飽和后，用蒸汽對納米吸附劑進(jìn)行脫附再生，二溴丙烷蒸汽能夠冷凝回收。<br />
具體流程說(shuō)明為：車(chē)間二溴丙烷廢氣先經(jīng)過(guò)引風(fēng)機抽取后，進(jìn)行二級冷凝，一級冷凝溫度在25℃左右，二級冷凝溫度在10℃左右。冷凝液化后的二溴丙烷用儲罐接收，未冷凝下來(lái)的二溴丙烷廢氣接入裝有納米吸附劑的吸附塔進(jìn)行吸附富集（吸附溫度為常溫，吸附壓力為~2kpa），廢氣經(jīng)過(guò)吸附后可達標排放。吸附劑吸附飽和后，將低壓蒸汽通入吸附塔進(jìn)行吹脫（溫度在100℃左右）。吹脫出的二溴丙烷和水蒸汽的混合物再經(jīng)過(guò)冷凝液化，靜置分層，可分離回收出二溴丙烷。蒸汽脫附后的納米吸附劑溫度較高，通入潔凈空氣冷卻降溫至室溫后，可重新用于吸附。吸附塔通常配置為3臺，2臺用于吸附，1臺用于脫附備用。實(shí)際工程應用效果非常好。<br />
該工藝對于廢氣中的二溴丙烷去除率可達99%以上，并可以達標排放。<br />
附HDV型納米吸附劑優(yōu)點(diǎn)：<br />
(1) 孔結構可控且孔容積高；<br />
(2) 具有良好的物理化學(xué)穩定性，耐酸、堿和有機溶劑、具有較高的熱穩定性和機械強度，耐磨損；<br />
(3) 表面呈現高疏水性，濕度對吸附性能無(wú)影響；<br />
(4) 容易再生且吸附性能穩定；<br />
(5) 不需更換即無(wú)危險廢物產(chǎn)生。<br /></td>
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